201451. lajstromszámú szabadalom • Herbicid készítmények, és eljárás a hatóanyagot képező 1-metil-1H-imidazol-5-karbonsav-származékok előállítására

HU 201451 B

11

12

1. táblázat folytatása

(I) általános képletű vegyületek

Vegy.

száma

R1

R2

A

Z

Fizikai állandók

1.17

H

ch3

CiH7-n

4-C1-C6H6-.HNOs/125,4 °C

1.18

H

ch3

C3H7-n

2-OCH3-CőH4-op.: 77-78 °C

1.19

H

ch3

C2H5

4-CH3-C6H4-.HNOs/op.: 132-134°C

1.20

H

ch3

C2H5

4-OCH3-C6H4-gyanta

1.21

H

ch3

C3H7-n

2-CH3-C6H4-.HNOs/op.: 122-123 °C

1.22

H

ch3

C3H7-n

3-CH3-C6H4-gyanta

1.23

H

ch3

C2H5

2-CH3-4-CH3-C6H3-viszkózus olaj

1.24

H

ch3

C3H7-n

4-F-QH4-.HNOs/op.: 121,9 °C

1.25

H

ch3

C3H7-n

2-CH3-4-CH3-CőH3-viszkózus olaj

1.26

H

ch3

C3H7-n

2-Cl-4-Cl-C6H3-op.: 122-123 °C

1.27

H

ch3

C3H7-n

3-CI-C6H4-.HNO-s/op.: 108,5 °C

1.28

H

ch3

C3H7-n

4-CI-C6H4-1.29

H

ch3

C3H7-n

2-CI-C6H4-.HNOij/op.: 123,1 °C

1.30

H

ch3

C5Hn-n

4-CH3.C6H4-.HNOs/op.: 120-125 °C

1.31

H

ch3

C3H7-n

2-OCH3-5-F-CöH3-gyanta

1.32

H

ch3

C3H7-n

2-F-5-CH3-CöH3-.HN03/szilárd anyag

1.33

H

ch3

C3H7-n

2-CH3-5-CH3-CőH3-.HNOVop.: 149-150 °C

1.34

H

ch3

C5Hn-n

CeHs.HNOs/op.: 143-145 #C

1.35

H

ch3

GiH9-n

CeHs.HNOs/op.: 142-143 °C

1.36

H

ch3

GiHg-n

4-CH3-C6H4-.HNOs/op.: 122 °C(dec.)

1.37

SH

ch3

ch3

C6H5-op.: 131-134 °C

1.38

SH

ch3

H

C6H5-1.39

SH

ch3

H

3-Cl-4-Cl-C6H3-1.40

SH

ch3

C3H7-n

4-CF3-C6H4-op.: 193-193,5 6C

1.41

SH

ch3

C3H7-n

4-CH3-CóH4-op.: 209-211 °C

1.42

SH

ch3

C3H7n

2-OCH3-C6H4-op.: 156-158 °C

1.43

SH

ch3

C3H7-n

3-CF3-C6H4-op.: 108-111 °C

1.44

SH

ch3

C2H5

4-OCH3-C6H4-op.: 141-144 °C

1.45

SH

ch3

C2H5

4-CH3-C6H4-op.: 221-223 °C

1.46

SH

ch3

C3H7-n

2-Cl-4-Cl-H6H3-op.: 58-61 °C

1.47

SH

ch3

c2hs

2-CH3-4-CH3-QsH3-op.: 150-153 °C

1.48

SH

ch3

C3H7-n

2-CH3-4-CH3-C6H3-szilárd anyag

1.49

SH

ch3

CsHn-n

4-CH3-UH4-op.: 94-101 °C

1.50

SH

ch3

C3H7-n

3-CH3-C6H4-op.: 131-134 °C

1.51

SH

ch3

C3H7-n

2-OCH3-5-F-C6H3-op.: 174-176 °C

1.52

SH

ch3

C3H7-n

2-F-5-CH3-CőH3-op.: 125-127 °C

1.53

SH

ch3

C3H7-n

2-CH3-C6H4-op.: 171-173 °C

1.54

SH

ch3

C3H7-n

3-CH3-CőH4-szilárd anyag

1.55

SH

ch3

QHn-n

c6h5-op.: 108-109 °C

1.56

SH

ch3

C4H9-n

CőH5-op.: 143-144 °C

1.57

H

ch3

2-piridil

CőH5-.HNOs/op.: 137,6 °C

1.58

H

ch3

2-naftil

C6H5-op.: 96 °C

1.59

H

ch3

2-piridil

2-piridinil

1.60

H

ch3

3-piridil

CeHs-1.61

H

ch3

4-piridil

C6H5-op.: 137,8 °C

1.66

H

ch3

2-piridil

4-CI-C6H4-1.67

H

ch3

4-piridil

4-F-C6H4-1.68

H

ch3

C3H7-i

4-CH3-C6H4-gyanta

1.69

H

ch3

C3H7-í

4-OCH3-C6H4-gyanta

1.70

H

ch3

QHg-t

CőH5-1.71

H

ch3

C4H9-t

2-CH3-CeH4-1.72

H

ch3

C4H9-t

3-CH3-C6H4-1.73

H

ch3

C4H9-t

4-CH3-CőH4-1.74

H

ch3

GtH9-t

2-C2H5-C6H4-1.75

H

ch3

C4H9-t

3-CH3-4-CH3-CóH3-1.77

H

ch3-C(CH3)2-C2H5

c6h5-1.78

H

ch3

ciklohexil

c6h5-op.: 95-97 °C

7