201451. lajstromszámú szabadalom • Herbicid készítmények, és eljárás a hatóanyagot képező 1-metil-1H-imidazol-5-karbonsav-származékok előállítására

HU 201451 B

13

14

1. táblázat folytatása

(I) általános képletű vegyületek

Vegy.

száma

R1

R2

A

z

Fizikai állandók

1.79

SH

ch3

C3H7-i

4-CH3-C6H4-op.: 171-173°C

1.80

SH

ch3

c3h7-í

4-OCH3-CfiH4-op.: 110-112 °C

1.81

SH

ch3

C4H9-t

CeHsop.: 194-196 °C

1.82

SH

ch3

GjH9-t

2-CH3-CőH4-1.83

SH

ch3

C4H9-t

3-CH3-CeH4-1.84

SH

ch3

C4H9-t

4-CH3-CőH4-1.85

SH

ch3

G»H9-t

2-C2H5-C6H4-1.86

SH

ch3

C4H9-t

3-CH3-4-CH3-C6H3-1.88

SH

ch3

C(CH3)2-C2H5

C6H5-1.89

SH

ch3

ciklohexil

CeHsop.: 180-182 °C

1.90

H

C2Hs

C3H7-n

2-piridil

1.91

SH

C2H5

C3H7-n

2-piridil

1.92

H

CH2-CH/CH2

C3H7-i

c6h5-1.93

SH

CH2CH = CH2

C3H7-í

CöH5

1.94

H

CőHi3-n

ch3

3-CI-C6H4-1.95

SH

CßHi3-n

ch3

3-CI-C6H4-1.96

H

CőHucyc.

ch3

4-CI-C6H4-1.97

SH

CöHncyc.

ch3

4-CI-C6H4-1.98

H

ch2-c=ch

C2H5

CöH5-1.99

SH

ch2-c=ch

C2H5

CeHs-1.100

H

CH2-CsCH

QHj-t

2-piridil

1.101

SH

CH2-C 5 CH

C4H9-t

2-piridil

1.102

H

ch2-ch=ch2

C3H7-i

4-OCH3-CőH4-1.103

SH

ch2-ch=ch2

C3H7-í

4-OCH3-C6H4-1.104

H

ch3

C3H7-n

4-NO2-C6H4-1.105

SH

ch3

C3H7-n

4-NO2-C6H4-1.106

H

ch3

C3H7-i

4-NO2-C6H4-1.107

SH

ch3

C3H7-i

4-NO2-C6H4-1.112

H

H

H

c6h5-.HCl/op.: 211-215 °C

1.113

H

H

ch3

c6h5-op.: 187-189 °C

1.114

H

ch3

ch3

4-C1-C6H4-.HCl/op.: 147-148 °C

1.115

H

ch3

C2H5

c6h5-.HCl/op.: 167-168,5 °C

1.116

H

C3H7-n

ch3

c6h5-.HCl/op.: 156-157 °C

1.117

H

C3H7-i

ch3

C6H5-.HCI/op.: 192-193,5 °C

1.118

H

ch3

ch3

4-Br-C6H4-.HCl/op.: 137-139 °C

1.119

H

ch3

ch3

4-F-C6H4-.HCl/op.: 174-175,5 6C

1.120

H

ch3

ch3

3-CH3-4-CH3-CőH3-.HCl/op.: 166-167 °C

1.121

H

ch2-c=ch

ch3

C6H5-op.: 92-92 °C

1.122

H

ch3

ch3

2-CI-C6H4-.HCl/op.: 181-183 °C

1.123

H

ch2-ch=ch2

ch3

CeHs.HCl/op.: 134-136 °C

1.124

H

C5Hn-n

ch3

CeHs.HCl/op.: 139-140 °C

1.125

H

ch3

ch3

3-piridil

,2HCl/op.: 178-189 °C(dec.)

1.126

H

H

C2H5

CeHs.HCl/op.: 142-151 °C(dec.)

1.127

H

ch3

ch3

4-piridil

op.: 79-80 °C

1.128

H

ch3

ch3

2-piridil

.2HCl/op.: 183,5-186,5 °C

1.129

H

H

ch3

4-CI-C6H4-op.: 188-189 °C

1-130

H

H

ch3

4-CH3-CeH4-op.: 191,5-193 °C

1.131

H

H

ch3

3-CI-C6H4-op.: 165,5-167,5 °C

1.132

H

H

ch3

2-CI-C6H4-op.: 224-225,5 °C

1.133

H

H

ch3

3-CH3-4-CH3-CeH3-op.: 216-218 °C

1.134

H

H

ch3

4-Br-CeH4-op.: 193-194,5 °C(dec.)

1.135

H

H

ch3

4-CH30-CeH4-op.: 144,5-148 °C

1.136

H

H

ch3

4-F-C6H4-op.: 190,5-194 °C (dec.)

1.137

H

C3H7-i

ch3

4-F-C6H4-.HCl/op.: 190-191,5 °C

1.138

H

C2H5

ch3

CeHspikrát/op.: 114-115,5 °C

1.139

H

C2H5

ch3

4-F-C6H4-.HCl/op.: 113-114 °C

1.140

H

ch2-ch=ch-ch3

ch3

CeHs

.HCl/op. 139-140,5 °C

8