191617. lajstromszámú szabadalom • Eljárás ciklopropánkarbonsav-származékok előállítására
3 191 617 4 I. táblázat A vegyület sorszáma R1 R2 0 Konfiguráció NMR-spektrum vonalai (5), ppm 1.-cf3 Cl-OC,Hs cisz/transz i ,20 1,40 (ni, 9H), 1,48- 2,77 (m, 211), 3,96-4,23 (m, 2H), 6,15,6,95 (2d, 1H) 2.-cf2ci-Cl —OC2 h5 cisz/transz 1,15-1,55 (m,9H), 1,55-2.50 (m, 2H), 4,00-4,33 (m, 2H), 6,13 6,95 (dd, 1H) 3.-CF2C1-F-oc2hs cisz/transz 1,20-1,58 (m, 9H), 1,58-2,33 (m, 2H), 4,15 (q,2H), 5,10, 5,41,5,91,6,25 (4d, 1H) 4.-cf3-Br-oc2h5 cisz/transz 1,10-1.40 (m, 9H), 1,60-2,44 (m, 2H), 3.96 4,28 (m, 211). 5,96 -7,26 (m. Ili) 5.-cf2cf3-Cl-oc2h5 cisz/transz 1,15-2,53 (komplex, 11H), 3,92-4,30 (ni, 2H) 6,12, 6,92 (dd, 1H) 6.-cf2cf2ci-Cl —OC2 H5 cisz/transz 1,20-1,41 (m, 9H), 1,62-2,48 (m, 2H), 3,95-4,24 (m, 2H), 6,15,6,95 (2d, 1H) 7.-cf3-cf3-OH cisz/transz 1,27-1,47 (m, 6H), 1,60-2,67 (ni, 2H), 6,36 7,25 (2d, 1H) 8.-cf3-cf3-Cl cisz/transz 9.-C*3-Cl-OH cisz/transz 1.20-1,46 (m, 6H), 1,67-2,63 (m, 2H), 6,17-6,88 (2d, 1H) 10.-cf3-Cl-Cl cisz/transz 1,32-1,43 (ni, 6H), 3,24-2,68 (m, 2H), 5,84-6,72 (ni, 111) 11.-chf2-cf3-OH cisz/transz 1,30-1,50 (ni, 6H), 1,76-2,56 (m, 2H), 6,28, 7,02 (2d, 1H), 6,36 (m, 1H) 12.-chf2-chf2-OH cisz/transz 1,30-1,50 (m, 6H), 1,70-2,60 (komplex, 2H), 5,70-7,13 (komplex, 3H) 13.-ch3-cf3-OH cisz/transz 1,22-1,44 (m, 6H), 1,6-2,3 (m, 5H), 5,36-6,6 (rr, 1H), 11,9 (s, 1H) 14.-cf2ci-cf2ci-OH cisz/transz 1,24-1,42 (m, 6H), 1,80-2,68 (m, 2H), 6,16, 7,12 (dd, 1H), 11,6 (s, 1H) 15.-chf2-ccif2-OH cisz/transz 1,28-1,52 (m, 6H), 1,74-2,54 (m, 2H), 6,20, 7,22 (2d, Hl), 6,30 (ni, 111) 16.-cf3-Br-OH cisz/transz " 1,20-1,50 (m, 611), 1,70-2,50 (m, 2H), 6,08-7,04 (m, 1H) 17.-cf2ci-F-OH cisz/transz 1,22-1,48 (m, 6H), 1,77-2,55 (m, 2H), 6,20, 6,92 (2d, 1H) 18. —cf2ci-Cl-OH cisz/transz 1,22-1,48 (m, 6H), 1,77-2,55 (m, 2H), 6,20, 6,92 (2d, 1H) 19.-cf2ci-Cl-OH cisz 1,25 (s, 6H), 1,80-2,25 (m, 2H), 6,73 (d, 1H) 20.-cf2cf3-Cl-OH cisz/transz 1,10—1,50 (m,6H), 1,68-2,58 (m,2H), 6,14, 6,85 (dd, 1H) 21.-cf2cf2ci-Cl-OH cisz/transz 1,20—1,49 (m, 6H), 1,72-2,56 (m, 2H), 6,15 6,87 (2d, Hl) 3
