176254. lajstromszámú szabadalom • Eljárás helyettesített fenil-guanidin-származékok előállítására

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176254

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6.3. példa:

R = 3-Cl, R2 = -CH3, R2 = -COOC2 Hs, R3=-COOC2Hs,

6.4. példa:

R = 3-Cl, R1 = -CH,, R2 = -COOC,H7,

R3 = -COOC3H7,

6.5. példa:

R = 3-Cl, R* = -CH3, R2 = —COOCH3,

R3 = -COOC2 Hs,

6.6. példa:

R = 3-Cl, R‘ = -CH3, R2 = -COOCH,,

R3 = -COOCéH, !,

6.7. példa:

R = 3-Cl, Rl = - CH,, R2 = -COOCH,,

R3 = -COC2Hs,

6.8. példa:

R = 3 -Cl, R1 = -CH3, R2 = -COOCH,,

R3 = -COCH2OC2Hs,

6.9. példa:

R = 3-Cl, R*'= —CH3,

R2 = -COOCH2CH=CH2,

R3 = -COOCH,,

6.10. példa:

R = 3-Cl, R1 = -C,H7,R2 = -COOCH,, R3 = -COOCH,,

6.11. példa:

R = 3-Cl, R' = -CH2OCH,.

R2 = -COOCH3, R3 = -COOCH,.

6.12. példa:

R = 2 —CI, R1 = -C,H7, R2 = -COOCH,. R3 = COOCH,,

6.13. példa

R = 2,5 Cl, R1 = -CH,,R: = COOCH,. R3 = -COOCH3.

6.14. példa

R = 3,5—Cl, R1 = —C3H7 ;l

R2 = -COOCH.,, R3 = - COOCH,,

a (XV) vegyidet 170 °C-on olvad,

6.15. példa

R = 4—Br, Rl s CH,. R2 = -COOCH,,

R' = COOCH,,

6.16. példa:

R = 3- Br, R1 =-C2Hs,R2 =-COOCH,, R3 = -COOCH,, a (XV) vegyidet 158 °C-on olvad,

6.17. példa:

R = 3-Br, R1 = -C,H7,R2 = -COOCH,, R3 =-COOCH,,

6.18. példa:

R = 3-Br, R1 =-CH2OCH3,

R2 = -COOCH,, R3 = -COOCH,,

6.19. példa:

R = 2—Br, R1 = -CH3, R2 = -COOCH,,

R3 = ~COOCH3,

6.20. példa:

R = 4-CH3, R1 = -CH3,

R2 = -COOCH,, R3 = -COOCH,, a (XV) vegyidet 149 úC-on olvad,

6.21. példa:

R = 3—CH3, R1 = -CH,, R2 = -COOCH,, R3 =-COOCH,, a (XV) vegyidet 142 °C-on olvad,

6.22. példa:

R = 3-CH3, R1 = -C2 Hs, R2 = -COOCH3, R3 =-COOCH,,

6.23. példa:

R = 3—CH3, R1 = -C3H7, R2 = -COOCH,, R3 = -COOCH3,

6.24. példa:

R = 3—CH3, R1 =-CH20CH3,

R2 = -COOCH3, R3 = -COOCH,,

6.25. példa:

R = 2-CH3, R1 = -CH3, R2 = -COOCH,, R3 = -COOCH3,

6.26. példa:

R = 4—tere. bu, R1 = —CH3,

R2 = -COOCH3, R3- = -COOCH,,

6.27. példa:

R = 2,4—CH,, R* =-CH3,

R2 = -COOCH,, R3 = COOCH,,

6.28. példa:

R = 2-C1—4—CH,, R1 = —CH,

R2 = - COOCH,, R3 = -COOCH,,

6.29. példa:

R = 3,4-Cl, R1 = —CH,,

R2 = -COOCH,, R3 = -COOCH,, a (XV) vegyidet 149 °C-on olvad,

6.30. -példa:

R = 3-CF,, R1 =-CH,, R2 =-COOCH,, R3. = -COOCH,, a (XV) vegyidet 131 °C-on, a (XVI) vegyidet 151 °C-on, a (XVII) vegyidet 106 °C-on, a (XVIII) vegyidet 185 °C-on olvad,

6.31. példa:

R = 3—CF,, R1 =-CH2OCH3,

R2 = -COOCH,, R3 = -COOCH,, a (XV) vegyidet 131 °C-on, a (XVI) vegyület 116 °C-on, a (XVIII) vegyület 129 °C-on a (XVII) vegyület gyantaszerű termék,

6.32. példa:

R = 3-CF, ,R3 = -C2 H,, R2 = -COOCH, R3 = -COOCH,, a (XVI) vegyület 146°C-on, a (XVII) vegyület 112 °C-on, a (XVIII) vegyület 180 °C-on olvad,

6.33. példa:

R = 3-CF,, R1 =-C,H7,R2 = -COOCH,, R3 = -COOCH,, . a (XVI) vegyület 1Ó0 °C-on, a (XVII) vegyület 90 °C-on, a (XVIII) vegyület 163 °C-on olvad,

6.34. példa:

R = 3-CF,, R1 =C,H7,

R2 = COOC2H5 R3 = COOC2H5

6.35. példa:

R = 3—CF,, R1 =-C,H7,

R2 = -COOCH,, R3 = -COC2H5,

6.36. példa:

R = 3-CF,, R1 = -C,H7,

R2 =-COOCH,,

R3 = -COOCH2CH=CH2

6.37. példa:

R = 3—CF,, R1C,H7, R2 =-COOCH, R3 = -COOCH, CH^CH,

6.38. példa:

R = 4—OCH,, R1 =-CH,,

R2 =-COOCH,,

R3 =-COOCH,,

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