160215. lajstromszámú szabadalom • Eljárás fenoxikarbonsav-származékok előállítására

160215 12 (nC4

H9)2Ci[o-:(C

6

H

3

mCl)-0-C(CH

3

)2COOH]2 (CH3)(nC5H11

)C.[D-C

6

H

4

OC(CH3)2COOH]2 (CH3)(nC5H11

)C{p-C

0

H4OG(iCH

3

)

2

COOC

2

H5]2 (CH3

)

(nC5Hu)C [p-C6

H40G(CH

3

)9CONH2]2 (CH3)(nC5H11

)C[p-C

6

H

4

OC(CH3)r(C

2

H

5

)COOH]2 (C2H5)(nC5H11

)C[p-C6H40G(CH

3

)2COOH]

2 (1

nC3H7)(nC5H

11

)C{p-C6H40C

1

(CH

3

)2COOH]2 (nC4H9

)(nCr

J

H

11

)Ci[ip-C6H40C(CH

3

)

2

COOH]., (nC5H1!

)

2

Ci[p-C

6

H40C(CH

3

)2COOH]

2 (CH3)(inC6

H

1

3)C[p-C

6

H40C(CH3)

2

COOH]2 (C2H5).(nC6

H

13

)C[p-C6H400(CH3)

2

COOH]2 (nC3

H7>(nC

c

H,

3

)C[p-C

6

H

4

OC

(CH3

)

2

COOH]

2 (CH3)<nC7H15

)C[p-C«iliOC(CH3)2COOH]2 (C2H5)(nC7

H

15

)C

!

[p-CfiH40Ci(iCH3)

2

COOH]2 (CH3){nC8H1

7)Ci[p-C6H40C(!CH3)

2

COOH]

2 (CH3)(iC3H7)Ci[p-C6H40C(CH3

)2COOH]

2 (CH3

)

[CH(CH3)!(C2

H5)]

C[P-CGH4

OC(CH3)2COOH]2 (.iC3H7)20[p-CcH4

OC!(CH3)2COOH]2 (CH3)i(C6H5)Cfp-C6

H40!C(CHo)

2

COOH]2 (CH3){C6

H

5

)C.[p-C

6

H40C<CH3)2COOC2H5]2 (CH3)i(C6

H

5

)C[p^C

6

H40C(CH3)2CO.NH2]2 (CH3)i(C6

H5)0[:p-C

c

H40C(CH3);(C2H

5

)COOH]2 (C6

H

5

)2C [p-C

6

H

4

OC(CH

3

)

2

COOH]

2 (CH3);(C6

H

5

CH2)C[P-CGH40C(!CH3)

2

COOH], (C6

H5CH2)2C[P-CGH40G(CH3)2COÖH3

, (C6H5)(CoHfeCH2)C[p-C6HíOG(CH3)2CÖOH]2 (CH3)i(C6

H

11

)C[ip-CfiH40C(CH

3

)2COOH]

2 (CeHiOaOfp-CeHiOOiCHaJaCOOH^ (C6HU).(CGH5

CH

2

)0[IP^C

6

H40C(CH3)2COOH], (CH3)(C5H9

)C[P-CGH40C(CH

3

)2COOH]2 (CH3)(C7H1

3)C

l

[p-C

6

H40C(C:H

3

)

2

COOH]2 (Cr>Hr)

).(C5H

9

)C:[p-CcH40C;(CH3),COOH]

2 (C5

Hs)2iC[p-C

6

H40G(CH3)2COOH], (CBH^XCTHI 3>C [p-C6HíOO(CH

3)2COOHl

2 (CH2

)

[P-CGH40!C(CH3)2COOH3

]

2 C,H2[p-CoH40G(GH3)i(C2

H5)COOCH3]2 CH2[pHCfi

H40C(C

2

H5) (C

2!

H5)COOC

2

Hr]

2 CH2[P-.(CGH3OC1)-0-G(CH3

)

2

COOCH3]^ CH2

[p-(C6H30l)-O-G(CH3)

2

COOC.,Hr,]

2 CH3

CH[p-C

6

H400(CH3)2COOC2H

3

]

2 (CH3)2

G[jp-CpH

4

OC(GH3)2COQCH.

)

], (CH3)2C![p-GsH40G(CH3)(C2H5)COŐCH3

], (CH3)2

C[p-C6H400(C2H5)

2

COOCoH-j7 CH2[0-:(C(i

H

3

mCl)-O-C(CH

3

)

2

COÓC2H

5

]-) CH2

:[o-(C

6

H3mCl)-0-C(C2H5)2-COOC2H

5

]., (CH3)20[nn(C6

H

3

oCl)-0-C(CH3)9COÓC.;Hr

)

].

t (CH3)(C2H5)C[p-C6

H

4

OC(CH

3

)2COOCH3]2 (CH3

)(C

2

H

5

)C[p-CoH40C(GH3)(C2H

5

)COOC

?

H

5

]

2 (CH3

>(C2H5)Cto-;(C

(

,;H;

l

m[Cl)-0-C{CH

3

),COOC2H5]2 (CH3

)(C2H5)C[o-(C

6

H

3

mI)-0-C(CH3)2COOC2Hr

>

]2 (C2H5)áC[p-CG

H

4

OC{CH3)2COOCH

3

]9 (C2H5)2C[ip^C6H40C(CH3

):(C

2

H5)COÓCH3]9 (C2H5)2C[PHC6

H40C(C

2

H

3

)2COOC

2

H

5

]

2 (C2

H5)

2

C[o.-!(CfiH3mCl)-0-C(CH:>)2COOC2H5]2 (CH3

>(inC3H7)C[p-CGH

4

OC.(C.H3)-)

COOCH3]2 (CH3)!(inC3H7)C[p-C6

H40G(CH3)i(C2H

5

)COOC2H

5

)2 (CH3

)(niC3H7)C[

1

o-(CGH3mCl)-O^G(CH3)

2

COOC2H5]., (C2H5)i(nC3

H7>C[p-C6H

4

0-C(CH3)2COÓCH3)2 (C2H5)(CH2

!CH2CH3)C{P-CGH,

1

OC(CH

!

)(C,,H-,). CQOC2

H

3

]

2 fC2H5)(nC3

H

7

)iO[o-:(C

6

H3mCl)-0-Ci(CH

3

)9-COOC2

H

3

]

2 (nC3

H7)

2

C[p-C

6

H

4

OC(CH

3

)2COOCH

3

], (nC3

H

7

)

2

C •[p-C6H

4

00(CH3):(C2H5)COÓC

2

H5] 2 (nC3H7)2C{0-:(C6H

3

mCl)-O-G(CH

3

)2COOC2H5]2 (CH3

)(inC3H

7

)C[p-C6H40C(CH

3

)2COOCH

3

]2 (CH3

)(nC

4

H9)C

1

[p-C

6

H

4

OC;(CH

3

)(C

2

H

5

)COOC

2

H5]2 (CH3

XnC/

1

H9)G[p^C

6

H

4

00<C2H5)2COOC2H5l2 <C2H5

)(nC4H9)C[o-(C6H3mCl)-0-Ci(CH3)i(C2H

5

)-5 COOCHsh (nC3H7)<nC4

H9)C[p-C6H

4

0!Ci(CH

3

)

2

COOCH3]2 (nC3H7)<n,C4H9

)G[p^CGH40Ci(OH3)(C2H5)COOC2H

5

]

2 (nC3

H7)!(nC4H9)C[o-(C

6

H

3

mCl)-0-C(GH3)

2

COOC2

H

3

]9 10 (nC

4H9)

2

0[p-C6H40C(CH3)2000CH

3

]2 (!nC4H9

)2C[p~C

6

H40C!(CH3)

^HrOCOOCaHj] 2 (nC4H9)2Ci[o-.(C6H3'mCl)-O^Q(CH3)2COOC2H

5

]2 (CHsXinCr.Hu )G[p-CcH4

OC

(CH^COOC&s}, (CH3),(nC5Hll

)0[p-C

(

iH40C(CH3)(C2H

5

)COdC2H5)2 15 {C2H5) (nCsHj 1)C[p-C

6

H40C(CH

3

)

2

COOC

2

H

r>

]

2 (nC3H7)(nC5H11

)0[:p-C6H40C(CH3)

2

COOC2H

5

]2 (nC4

H

9

) (inC.-.Hi

i)C :[p-C6H4

OG(CH3)2COOC9H

5

]

2 (nCsHt 02C{p-C6H

4

OC(CH

3

)

2

CQOC

2

H

5

]

2 (CH3)i(nCßH,3

)C[p-CGH40C(CH3)

2

COOC

2

H

5

]

2 20 (C

2H5)(nC6H

1

3)C[p-CßH40C(CH

3

)

2

COOC

2

H

5

]2 (nC3H7)

i

(nC

6

H

13

)C[p-CfiH40C(CH

3

)2COOC2H

5

]2 (CH3)(bC7H13

)C[p-CGH40C(CH3)2COOC2H5]2 (C2H3

)(nC

7

Hi5)ClC

6

H40C(CH

3

)

2

COOC

2

H

3

]9 (CH3

)(nC

g

H

1

7)C[p-C

6

H40C(CH

3

)

2

COOC2H

3

]2 25 (CH

3XnC

8

H|7)C[p^C6H

4

OG(CH

3

)2CONHCH3]2 (CH3)(iC3H7)Ci[p-C6H40C(CH3)2COOC2

H

3

]

2 (CH3)(CH(CH3XC2

H

5

]G[ip-C,!H40C(CH3

)

2

COOC

2

H

5

]

2 (iC.3

H

7

)2C[p-C6H40C(CH

3

)2COOC2H

3

]2 so (CH3

)

(C6

H5)G[p-C6H40G(CH

3

)2COOCH

3

l

2 {CH3

)(C

6

H

3

)C:[p-C6H40C(CH

3

)2COOC

2

H5]2 (Cf)H5)9C[

l

p-C

6

H40C(CH

3

)

2

COÖC2H

5

]2 (CH:0(C,;H3CH2)C[p-JC

6

H

4

OC(CH3)2CÓOC

2

Hrj2 (CGH3CH9)

2

C[P-C6H

4

OC(CH

3

)2COOC2H

3

]9 „5 (C

6H

3

):(C

6

H

3

CH

2

)C [p-CeHíOCíCHaJzCOOCaHsh (CH^XCeHiOGfp-CeHiCÄiCHsJaCOOCzHa], (C6H5)(C6H

n

)C[p-CcH40G(CH3)2COOC

2

H

5

]9 (C6H

11

)9C[p-C

6

H40C(CH3)2COOC

2

H

3

]2 (CeHii )2(CGH5

CH

2

)C

[P-CGH40C(CH3

)

2

COOC

2

H

5

]

, .„ (CH

3XC

3

H9)G[p-C„H40C (CH3)

2

COOC2H

3

]2 (CH3XC7Hi3)C[p-C6

H40C(CH3)

2

COOC

2

H

3

]2 (CH3

)

(C7

Hi3)C![p-C

c

H/

l

OC (CH3)

2

CON(C9H

3

),] •, (CßH3)(C5H9)C[

i

p-CfiH40C(CH

3

)2COOC

2

H

3

]2 (C5H9)2C[P-CGH40C<CH3)2COOC9H

5

]

2 (C5H9) (C7Hi3)G[p-C

6

H40C

i

(CH

3

)

2

COOG2H

3

]

2 B-[CH2

COOH]2 B-[CH(CH3)c6oH]2 B-tCH(C9H3

)COOH]

2 B-[CH<nC:

.H

7

)COOH]

2 B-[CK{iC,H7

)COOH]

2 B-[CH(nC4

H9)COOH]

2 B-[CH<iC/iH9)COOH]2 B-[CH(iCiPIr))COOH]2 B-rC(CH;,)2

COOH]

2 B-{0(CH3

XC

2

H

5

)COOH]

2 55 B-[C(CH

3)i(:nC

3

H

7

)COOH]2 B-[G(CH3

)

(iC;jH7

)COOH]

2 B-fjC (CH3

)

1

(nC

4

H

9

),COOH]

2 BJ[C(CH3

)<i-C

4

H

9

)COOH]2 B-[C(CH3

),(tC

4

H

9

)COOH]2 60 B-[C(C

2H

3

)

2

COOH], B-:[C (C2

H

3

)(nC3H

7

)COOH]

2 B- [C(C2

H

3

XiC

3

H

7

)COOH]2 B-[C(C2

H

3

)

(n.C4

H

9

)COOH] 2 65 B-[C(C2H

3

>(iC

4

H

9

)COOH]2 .6