Fogorvosi szemle, 2006 (99. évfolyam, 1-6. szám)

2006-04-01 / 2. szám

59 FOGORVOSI SZEMLE ■ 99. évf. 2. sz. 2006. lehetővé tették számunkra az AFM vizsgálatok elvég­zését és a Szilárdtest és Radiokémiái Tanszéknek az XPS vizsgálatokban nyújtott segítségért. A kísérlete­ket az Európai Unió 5. Keretprogramjának GRD3-2001- 61801 (SIMI-NAS) pályázata támogatta. Irodalom 1. Bertóti I, Marosi Gy, Tóth A: Műszaki felülettudomány és orvos­biológiai alkalmazása. V+V Lap és könykiadó kft., 2003; 120-125. 2. Boere G: Influence of fluoride on titanium in an acidic environment measured by polarization resistance technique. J Appl Biomater 1995; 6(4): 283-288. 3. Bollen CML, Papaioannou W, Van Elderle J, Schepers E, Quirynen M, Van Steenberghe D; The influence of abutment surface roughness on plaque accumulation and peri-implant mucositis. Clin Oral Impl Res 1996, 7: 201-211 4. Handbook of X-Ray photoelektron Spectroscopy. Perkin-Elmer Corporation, 1978. 5. Harzer W, Schroter A, Gedränge T, Muschter F: Sensitivity of titanium brackets to the corrosive influence of fluoride- containig tooth­paste and tea. Angle Orthod. 2001 ; 71 (4): 314-323. 6. Huang H: Effect of fluoride and albumin concentration on the corro­sion behavior of TÍ-6AÍ-4V alloy. Biomaterials 2003; 24: 275-282. 7. Huang H: Effects of fluoride concentration and elastic tensile strain on the corrosion resistance of commercially pure titanium. Biomate­rials 2002; 23: 59-63. 8. Keresztes Zs, Kálmán E, Ernst A, SzÉkÁcs A: Atomierő mikroszkóp alkalmazása OWLS alapú immunszenzor felületének vizsgálatára. Biokémia2004; XXVIII: 2-4. 9. Könönem MHO, Lavonius ET, Kivilahti JK: SEM observation on stress corrosion cracking of commercially pure titanium in a topical fluoride solution. Dent Mater 1995; 11:269-272. 10. Nakagawa M, Matsuya S, Shiraishi T, Ohta M: Effect of fluoride concentration and pH on corrosion behavior of titanium for dental use. J Dent Res 1999; 78(9): 1568-1572. 11. NakagawaM, MatsuyaS, Udoh K: Corrosion behavior of pure tita­nium and titanium alloys in fluoride-containing solutions. Dent Mat J 2001; 20(4): 305-314. 12. Neubert R, Eggert F: Fluoridhaltige Zahnpasten, Dtsch Apoth Ztg 2001; 141: 42. 13. NIST XPS Principal Photoelectron Lines Result. http:/srdata.nist. gov/xps 14. Ratner BD: An induction to Materials in Medicine Biomaterials Science. Academic Press, 1996; 23-28 15. Reclaru L, Meyer JM: Effects of fluorides on titanium and other dental alloys in dentistry. Biomaterials 1998; 19:85-92. 16.Strietzel R, Hösch A, Kalbfleish H, Buch D: In vitro corrosion of titanium. Biomaterials 1998; 19:1495-1499. 17. Toumelin-Chemla F, Rouelle Ff, Burdairon G: Corrosive proper­ties of fluoride-containing odontologie gels against titanium. Journal of Dentistry 1996; 24: Nos1-2, pp. 109-115. Dr. Stájer A, Dr. Radnai M, Dr. Pelsôczi K I, Dr. Turzó K, Dr. Oszkó A, Dr. Fazekas A: The effect of fluorides on the surface structure of titanium implants The high fluoride concentration and the acidic pH in tooth-paste used to prevent caries may modify the surface structu­re of implants made of titanium. Oxidative agents thicken and condense the titanium-dioxid layer on the surface of tita­nium and improve its stability against corrosion effects, while reductive agents like fluoride may have the opposite effect and attack this layer. The aim of the present work was to study the effects of fluoride containing toothpaste and gel on the titanium dioxid layer of titanium. The surfaces of the titanium (commercial pure grade I.) discs were treated with tooth­paste and gel containing 0.125 % and 1.25 % fluoride, respectively. The changes in the surface structure were analyzed by atomic force microscope (AFM) and X-ray photoelectron spectroscopy (XPS). Our results demonstrated that fluoride strongly binds to the titanium surface and modifies its structure in case of fluoride containing gels. Key words: dental implants, titanium surface, fluoride, corrosion, photoelectron-spectroscopy, atomic force microscope

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