200587. lajstromszámú szabadalom • Orto-szubsztituált karbonsav-benzil-észtereket tartalmazó gombaölőszerek és eljárás a hatóanyagok előállítására

HU 200587 B

166. Z= a,ß-dimetil-fenetil

167. Z= ß-fenil-fenetil; 8= 3,12 (d. 2H), 3,72 (s, 3H), 3,83 (s, 3H), 4,62 (t, 1H), 4,99 (s, 2H), 7,31 (m, 14H), 7,60 (s, 1H); olaj

168. Z= 4-terc-butil-fenetil

169. Z= 4-terc-butil-a-metil-fenetil; 6= 1,16 (d, 3H), 1,30 (s, 9H), 2,72 (m, 2H), 3,02 (m, 1H), 3,70 (s, 3H), 3,82 (s, 3H), 5,00 (s, 2H), 7,18 (m, 8H),

7.60 (s, 1H); olaj

170. Z= 2-klôr-fenetil

171. Z= 3-klôr-fenetil

172. Z= 4-kldr-fenetil

173. Z= 2-fluor-fenetil

174. Z= 3-fluor-fenetil

175. Z» 4-fluor-fcnetil

178. Z= sztiril

179. Z= 2-kldr-sztiril; 6= 3,67 (s, 3H), 3,76 (s, 3H), 5,19 (s, 2H), 6,44 (d, 1H), 733 (m, 8H), 7,60 (s. 1H), 8,09 (d, 1H); olaj

180. Z= 3-klôr-sztiril

181. Z=4-kl6r-sztiril

182. Z= 2,6-diklôr-sztiril

183. Z= 2,4-diklôr-sztiril

184. Z= 2-fluor-sztiril; olaj

185. Z= 3-fluor-sztiril

186. Z= 4-fluor-sztiril

189. Z= 2-metil-sztiril

190. Z= 4-metil-sztiril

191. Z= 4-izopropil-sztiril; olaj

192. Z= 4-terc-butil-sztiril; olaj

200. Z= 3-fenil-butil

201. Z= 2-metil-3-fenil-propil

202. Z= l-metil-3-fenil-pippil

203. Z= 3-(o-klôr-fenil)-propil 204.21= 3-(p-kl<5r-fenil)-propil

207. Z= 3-(p-terc-butil-fenil)-propil

208. Z= cinnamil; 5= 338 (d, 2H), 3,73 (s, 3H),

3,83 (s, 3H), 5,17 (s, 2H), 6,33 (m, 1H), 6,52 (d, 1H), 7,33 (m, 9H), 7,62 (s, 1H); olaj

209. Z= 4-fcnil-butil; 8= 1,65 (m, 4H), 235 (t, 2H),

2.60 (t, 2H), 3,65 (s, 3H), 3,70 (s, 3H), 5,03 (s, 2H), 739 (m, 9H), 733 (s, 1H); olaj

210. Z= 4-(o-kldr-fenil)-butil

211. Z= 4-(p-kldr-fenil)-butil; olaj

215. Z= 4-(o*tolil)-butil

216. Z= 4-(p-tolil)-butil

217. Z= 2-metil-4-fenil-butil

218. Z= 5-fenil-pentil; olaj

219. Z= 5-(o-tolil)-pentil

220. Z= 5-(p-tolil)-pentil

221. Z= 5-(o-kldr-fenil)-pentil

222. Z= 5-(p-klôr-fenil)-pentil

226. Z= 2-metil-5-fenil-pentiI; 5= 0,95 (d, 3H),

1,25 (m, 1H), 137 (m, 1H), 1,63 (m, 2H), 2,00 (m, 1H), 2,13 (m, 1H), 232 (m, 1H), 237 (m, 2H),

3,67 (s, 3H), 5,03 (s, 2H), 739 (m, 9H>, 7,56 (s, 1H); olaj

227. Z= 2,4-dimetil-5-fenil-pentil

228. Z= 2,4-dimetil-5-(p-terc-butil-fenil)-pentil; 8= 0,83,0,88,0,96 (3d, 6H), 1,19 (m, 2H), 1,31 (s, 9H), 1,79 (m, 1H), 230 (m, 4H), 2,60 (m, 1H),

3,69 (s, 3H), 3,81 (s, 3H), 5,03 (s, 2H), 735 (m, 8H), 737 (s, 1H); olaj

229. Z= 6-fenil-hexil

230. Z= 2-metil-6-fenil-hexil

7

231. Z= fenoxi-metil

270. Z= 2-metil-3-fenoxi-propil

271. Z= 4-fenoxi-butil;8= 1,88 (m, 4H), 2,45 (t,

2H), 3,74 (s, 3H), 3,88 (s, 3H), 4,01 (t, 2H), 5,09 (s, 2H), 7,18 (m, 9H), 7,64 (s, 1H); olaj

278. Z= 2-metil-4-fenoxi-butil

279. Z= 5-fenoxi-pentil

280. Z= 5-(ra-klôr-fenoxi)-pentil

285. Z= 2,2-dimeül-3-(2’3,-dinietil-fmil)-ciklopiopil; 5= 1,13,1,18,135,130 (4s, 6H), 1,73 (s, 6H), 1,88,2,08 (2m, 1H), 3,70 (s, 3H), 3,82 (s, 3H),

4,90,5,45 (2m, 1H), 5,05 (m, 2H), 7,38 (m, 4H), 7,62 (s, 1H); olaj

286. Z= 23-dimetil-3-(2,3,-diklôr-vinil)-cilclopropil; 5= 1,88,133,137,13O (4s, 6H), 1,13,1,88 (2d, 1H), 2,03,2,27 (2m, 1H), 3,70 (s, 3H), 3,82 (s, 3H), 5,03 (m, 2H), 5,62,630 (2d, 1H), 735 (m, 4H), 7,70 (s, 1H); olaj

287. Z= 23-dimetil-3-(2,,2’-dibrôm-vinil)-cikloptopil; 6= 1,19,134,138, Ul (4s, 6H), 1,68,1,88 (2d, 1H), 1,96,2,19 (2m, 1H), 3,72 (s, 3H), 3,83 (s, 3H), 5,04 (m, 2H), 6,16,6,81 (2s, 1H), 732 (m,

4H), 7,60 (s, 1H); olaj

288. Z= 23-dimetil-3-(2’-trifluor-metil-2’-klôr-vinil)-ciklopropil; 8= 134,139,132,135 (4s, 6H), 1,79,2,00 (2d, 1H), 2,17,2,44 (2m, 1H), 3,71 (s, 3H), 3,83 (s, 3H), 5,07 (m, 2H), 6,16,6,97 (2d,

1H), 7,36 (m, 4H), 7,60 (s, 1H); olaj

289. Z= 2,2-dikl<5r-3 3 -dimetil-ciklopropil; 5= 1,45, 1,49 (2s, 6H), 2,13 (s, 1H), 3,73 (s, 3H), 3,84 (s, 3H), 5,09 (s, 2H), 7,36 (m, 4H), 7,60 (s, 1H); olaj

290. Z= 2,2,3,3-tetrametil-ciklopropil

291. Z= 23-dimetil-3-(2’,2’-difluor-vinil)-ciklopropil

292. Z= 23-dimetil-3-(2,-trifluor-metil-2’-fluor-vinil)-ciklopropil

293. Z= 23-dimetil-3-(2’-metil2’-metoxi-karbohilvinil)-ciklopropil

294. Z= 2,2-dimetil-3-(4,,4’-diklôr-butadienil)-ciklopropil

295. Z= 23-dimetil-3-(r-brôm-2’3’3,-tribn5metil)-ciklopropil

296. Z=23-dimeül-3-(^-b^őm-2,3,-<likl6^-2,brôm-etil)-ciklopropil

297. Z= 23-dinietil-3-ciklopentilidén-metíl-ciklopropil

298. TJ l-(4’-etoxi-fenil)-23-diklôr-ciklopropil

299. Z= 23-dimetil-3-(4,-terc-butil-fenil)-ciklopn>pil

301. Z= l-(N-pirroIil)-2-metil-vinil; 8= 0,77 (d,

3 H), 0,98 (d, 3H), 2,42 (s, 1H), 3,69 (s, 3H), 3,80 (s, 3H), 4,18 (d, 1H), 5,03 (s, 2H), 630 (m, 2H),

6.83 (m, 2H), 7,31 (m, 4H), 738 (s, 1H); olaj

302. Z= 4-metil-5-(p-terc-butU-fenil)-l,3-pentadienil; 8= 13 (s, 9H), 232 (s, 3H), 3,43 (s, 2H), 3,72 (s, 3H), 3,87 (s, 3H), 5,13 (s, 2H), 5,88 (d, 1H),

6,10 (m, 1H), 6,45 (d, 1H), 735 (m, 8H), 7,63 (s, 1H); olaj

303. Z- 13-dimetil-butil

304. Z= 1 -ctil-3-metil-butil ; 8= 0,89 (m, 9H), 1,25 (m, 1H), 139 (m, 4H), 2,41 (m, 1H), 3,71 (s, 3H), '

3.84 (s, 3H), 5,03 (s, 2H), 736 (m, 4H), 7,59 (s,

1H); olaj

305. Z= 1 -(n-propil)-3-metil -butil; olaj

306. Z= l-izopropil-4-metil-pentil; olaj

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