192464. lajstromszámú szabadalom • Ciklohexenol származékokat hatóanyagként tartalmazó gyomírtószerek és eljárás a hatóanyagok előállítására

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184. példa

185. példa

186. példa

187. példa

188. példa

189. példa

190. példa

191. példa

192. példa

193. példa

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195. példa

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197. példa

198. példa 199 példa

200. példa

201. példa

R1 = 4-metil-ciklohex-l-én-5-il, X = H, R2 = n-propil, R3 = etil, A = benzoil ‘H-NMR spektruma: 0,85 (t), 5,62 (s), 8,18 (d)

Rl = 2-metil-l-ciklohexenil, X = H, R2 = etil,

R3 = etil, A = benzoil R1 = 2,6,6-trimetil-l -ciklohexenil, X = H, R2 = n-propil, R3 = etil, A = benzoil 1H-NMR spektruma: 0,85 (t), 1,75 (s),

8.05 (d)

R1 = 2,6,6-trimetil-l -ciklohexenil, X = H, R2 = n-propil, R3 = allil, A = benzoil 1 H-NMR spektruma: 1,05 (s), 4,50 (d),

7.6 (d)

R1 = ciklododeka4,8-dienil, X = H, R2 = n-propil,

R3 = allil, A = benzoil

R1 = ciklododeka-4,8-dienil, X = H, R2 =

etil,

R3 = etil, A = benzoil

‘H-NMR spektruma: 1,05 (t), 5,30 (m), 7,50 (m)

R1 = ciklohexil, X = H, R2 = n-propil, R3 = etil,

A = benzoil

‘H—NMR spektruma: 1,10 (t), 1,75 (m), 7,50 (m)

R1 = 4-metil-ciklohex-3-enil, X = H, R2 = n-propil,

R3 = etil, A = benzoil

'H-NMR spektruma: 0,85 (t), 1,65 (s),

5.35 (s)

R1 = 4-metil-ciklohex-3-enil, X = H, R2 = n-propil,

R3 = allil, A = benzoil

R1 = 4-metil-ciklohex-3-enil, X = H, R2 =

n-propil,

R3 = 3-klór-allil, A = benzoil

R1 = 4-metil-ciklohex-3-enil, X = H, R2 =

n-propil,

R3 = etil, A = 2-metil-benzoil 1 H-NMR spektruma: 1,10 (t), 2,60 (t),

5.35 (s)

R1 = 2,6,6-trimetil-biciklo-(3.1.1) heptán-3-il, X = H, R2 = n-propil, R3 = etil,

A = benzoil

1 H—NMR spektruma: 1,38 (q), 3,98 (q),

7,46 (m)

R1 = 2-metoxi-tetrahidro-pirán-5-il, X = H, R2 = n-propil, R3 = etil, A = benzoil R1 = 2-metoxi-tetrahidro-pirán-5-il, X = H, R2 = n-propil, R3 = allil, A = benzoil R1 = 4-metil tetrahidro-pirán-3-il, X = H, R2 = n-propil, R3 = etil, A = benzoil R1 = 4-metil-tetrahidro-pirán-3-il, X = H, R2 = n-propil, R3 = etil, A = 2-[4-/4-(trinuor-metil)-fenoxi/-fenoxi )-propionil R1 = 4-metil-tetrahidro-pirán-3-il, X = H, R2 = n-propil, R3 = etil, A = 2-[4-/4-jód-pirid-2-il-oxi/-fenoxi]-propionil R1 = tetrahidro-furán-3-il, X = H, R2 =

n-propil,

R3 = etil, A = benzoil

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202. példa R‘ = 5,6-dihidro-2H-pirán-3-il, X = H,

R2 = n-propil,

R3 = etil, A = benzoil

203. példa R1 = 2-metoxi-tetrahidro-pirán-6-il,X = H,

R2 = n-propil, R3 = etil, A = benzoil ‘H—NMR spektruma: 1,05 (t), 3,32 (s), 4,70 (s)

204. példa R1 = tetrahidro-pirán-3-il, X = COOCH3,

R2 = n-propil, R3 = etil, A = benzoil 'H-NMR spektruma: 0,88 (t), 3,75 (m), 7,45 (t)

205. példa R1 = 2-metil-pirid-6-il, X = H, R2 = n-propil,

R3 = etil, A = benzoil

‘H—NMR spektruma: 1,08 (t), 2,55 (s),

8,05 (d)

206. példa R1 = pirid-4-il, X = H, R2 = n-propil, R3 =

etil,

A = benzoil

‘H-NMR spektruma: 3,60 (m), 4,0 (q),

7,28 (m)

207. példa R1 = l-oxo-tetrahidro-tiopirán-3-il, X =H,

R2 = etil, R3 = etil, A = benzoil 1H—NMR spektruma: 1,85 (m), 3,45 (m),

4.00 (q)

208. példa R1 = l-oxo-tetrahidro-tiopirán-3-il, X = H,

R2 * n-propil, R3 = etil, A = benzoil

209. példa R‘ = 1,1-dioxo-tetrahidro-tiopirán-3-il, X

= H, R2 = n-propil, R3 = etil, A = benzoil

210. példa R1 = 1,1-dioxo-tetrahidro-tiopirán-3-il, X

= H, R2 = etil, R3 = etil, A = benzoil ‘H—NMR spektruma: 1,05 (t), 4,0 (q),

8.0 (d)

211. példa R‘ = l-(benzil-oxi)-etil, X = H, R2 = n-propü,

R3 = etil, A = benzoil

‘H—NMR spektruma: 0,90 (t), 3,55 (m),

7,35 (s)

212. pé da R‘ = l-[2-(n-butoxi)-etoxi]-etil, X = H,

R2 = n-propil, R3 = etil, A = benzoil 'H-NMR spektruma: 3,60 (m), 4,0 (q), 7,60 (m)

213 példa R1 = 2-[2-(n-butoxi)-etoxi]-etil, X = H, R2 = n-propil, R3 = etil, A = benzoil

214. példa R1 = 4-fluor-fenil, X = H, R2 = n-butil,

R3 = etil,

A = benzoil

'H—NMR spektruma: 1,35 (m), 4,0 (q), 7,05(t)

215. példa R1 = 3-metil-4-metoxi-fenil, X = H, R2

= n-propil,

R3 = etil, A = benzoil

'H-NMR spektruma: 2,14 (s), 3,88 (s),

8,10 (m)

216. példa R1 = 3-metil-fenil, X = H, R2 = etil, R3 =

etil,

A = benzoil

226. példa R1 = 2-izopropil-(l,3-dioxepán)-5-il, X =

H, R2 = n-propil, R3 = etil, A = benzoil,

227. példa R1 = 2-izopropil-(l ,3-dioxepán)-5-il, X =

H, R2 = etil, R3 = etil, A = benzoil

228. példa R1 = tetrahídro-pirán-3-il, X = H, R2 =

n-propil, R3 = etil, A = 2-(4-klór-fenil)-2- metil-propionil

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