160215. lajstromszámú szabadalom • Eljárás fenoxikarbonsav-származékok előállítására

160215 10 4-CH3-ci)klD-C6

H9![

!

p-CcH

4

OCH2COOC2H-,]

2 ciklo-C4He

i[p-C

6

H40C(CH3)!(C.>H5)COOC2H,-)

]2 ciklo-C4HB

i[:p-C

6

H40G(C2H5)2COOC

2

H5]2 3^Cl^c;iklowC4Hr)

[p-CoH40Ci(CH3)2COOC2H5]2 2-Cl^ciklo-C4H5i[p-CoH40G(ICH3)2COOC2H5]2 3-CH3-c;i1

klo-C4H3[p-C6H40G(CH3)2COOC2H5]2 2-CH3Hciklo-C4Ha[p^C6

H40G(CH

3

)2COOC2H

5

]2 3-GH3<áklo-C5

H

7

{p-'C6H

4

OC(CH3)2COOC2Hr

)

]2 3-C2H5

-ci:klo-C5Hv[p-C6H40G(OH

3

)2COOC2H5]2 .3-tJbuiráklo-C5

H

7

i[p^C

9

H

4

00(CH3)2|COOC2H3]2 3-ClHciklio-C5H7i[p-C6

H

4

OC!(CH3)2COOC2H

5

]2 3-F-ciklo-iC5

Hí[p-!C

6

H40Ci(CH3)2COOC2H5]2 3J-aiklo-C5

H

T

tp-C

6

H40C(OH3)2COOC2H5]2 3-CH30-ciklo-C9

H

T

[p-C

6

H40G(CH3)2COOC

2

H5]2 2-Cl-dklo^C5H7Íp-C6

H40G(CH3)2COO!C2H

r)

]

2 3-l

CH3HC!Lklo-C

5

,H7[p-C

6

H400(CH3)

i

(C

2

H5)COOC2

H

5

]2 2-CH3-ciklo-JC5

H7i[p-C

6

H40G(CH3)i(C2H5)COOC2H5

]2 3-Cl-ciMo-C5H^p-C6

H400(CH3)(C2H5)lOOOC

2

H

5

]2 3-CH30-ciklo-C5H7

ip-C

6

H40'G(CH

3

)i(C

2

H

5

)COQC2

H

5

]

2 3-CH3-ci:klo-C5H7![p-C6H40G(C2H5

)2COOC

2

H5]2 3-Cl-tciklo-C5H7[p^C6H40G(C2

H

5

)

2

COOC

2

H5]2 3-CH3O-cikl0-C5

H7i[p-C

6

H4OC(C2H5)2COOC2H5]2 2-Cl-ciklo-C5

H7i[p-C

6

H40C(C2H

5

)2COOC2H5]2 2,3-di-Cl-ciMo,-C5H6

[p-,C6H

4

OC

í

(CH3)2COOC2H5]2 2,3-di-CH3

-ciklo-C5H

6

{

P

-C

6

H

4

O0(OH3)2-COOC2

H

5

]2 3)

4-di-Cl-c!iklo^C5Hd[p-C

R

H40C(CH3)2COOC

2

H

5

]2 3,5-d.i-4CH3O-cikl!0-C5H

ö

[p-C

6

H4OC(CH

3

)2-COOC2

H

5

]2 2-Cl-3-CH3-iciklo-C5H

0

[p-CßH

4

OCi(CH3)2 COOC2

H5]2 3-CH30-4-C^cikk.-Cs

H6[p-C

6

H40C(CH3)2-COOC2

H5]2 öklo-C6H1d[p-C6H

4

OQ(OH3)2CONHCH{CH2C

e

H5)CßH5

]

2 4-CH3^ciklo^CeH9![p-C6H4

OG(GH3)

2

COOC

2

H5]2 4-Cl-ciklo-C6H9[p-C6H40G(CH3)áCOOC2H

5

]2 4-CH30-ciklo-C6

H

ö

[p^C

6

H40C(CH3)2COOC

2

H5]2 2^Gl^oiklo-C6Hö[p-C6

H40G(CH3)2COOC2H5]

2 2-C6

H5-ciklo-,C

6

H

9

![p-C6H40G(CH3)2COOC2H

5

]2 4-C6H5^oiklo.-CßH

ö

[p-C

6

H

4

OG(GH3)2COOC2H

3

]2 2-C1oH7-CLklo-C

6

H9[p-C

B

H40G(CH3)2COOC2H5]2 4-CioH7-ciklo-C6Híí[ip-C6H400(CH3)2COOC2H5]2 ciklo^C7H

12

:[p-C6H40C,(CH3)(C2H5)COOC2H5]2 .2-ClHCÍklo-C7H

11

í[p-C6H40G(OH3)2COOC2H5]2 3,4-di-Cl-]aiklK>-C7H1

d[p^CöH40G(CH3)

2

COOC2H5]

2 4-Cl-iciklo-C7

H

11

{p-C6H40G(CH3)

2

COOC

2

H5]2 2-CH3-cikli0HC7

H

11

tpjC6H4OC!(CH3)2COOC2H

5

]2 3.4-d:i-CH3

-oi

1

klo-C7H

1

d[p-C6H

4

OC!(CH3)2-COOC2H5

]2 4-CH3-ciklo-C7H11

i[p-C6H40C(CH3)2COOC2H5]

2 3,4-di-CH30-ciklo-C7Hio[p-C6

H

4

OCi(CH

3

)2-COOC2H5

]2 4-CH30-cikloHC7Hiil[p-Ce

H

4

OÜ(CH3)2COOC2H5]2 CH2[p-C6

H40Q(CH3)2COOH]

2 CH2[p^C6

H40C)(CH3)2COOC2H

5

]2 CH2[p-C6H40C(CH3

)2CONH2]2 CH2[p-C6H400(CH3

)2CO'NHCH(CH3)2]2 CH2[p-C6

H40C(CH3)(C2H

5

)COOH]2 CH2i[p-C6

H40Ci(C2H

5

)2COOH]2 CH2[p-CeH40G(eH3>(C2H5)eOOC2

H5]2 •CH2

;[IH[C

6

H30C1]-OC<!CH3)2C(XXH]2 10 15 20 25 30 35 40 45 50 55 60 65 CH2

[p-(C

6

H;soCl)OC<CH3)2COOC2H5J

2 CH4p-,(CB

H

3

oI)OC(CH

3

)2COOH]2 CH30Hl

[p-C6H

4

OQ(CH3)2COOH]

2 (CH3)20[p^C6

H

4

OG(CH3)2COOH]2 (CH3)20[p-CG

H

4

00(CH

3

)

2

COOC2H5]

2 {CH3

)20[p-C6H

4

OC(CH3)2CONH2]

2 {CH3)2Cl[p-C6

H40C(CH3)2COOC(CH

3

)

3

]2 (CH3

)2O[p-C

6

H40O(CH

3

)

2

C0NHCH2CH2CH3l2 (CH3

)

2

C![p-C

6

H400(CH3)(C

2

H

5

)COOH]

2 {CH3

)2a[pHCiH

4

OG(CH3)(C2H

5

)COOC2H

5

]2 (CH3)2C[[p-Q;

H400(CH3)

l

(C

2

H5)CONH2]2 (CH3

)20[PHC6H

4

00(C2H

5

)2COOH]2 CHato-iCßHämClJOOCCHaiaCOOHla CH2[o-(C6

H3mCl)-0-C(CH3)2COOC2H5]

2 CH2

(0^(CßH3mCl)-O-C[(CH3)2CONH

2

]2 CH2{o-i(C6H3

mCl)-O^C

l

(C:H3)(C2H5)COOH]2 CH2

[o-(C6H3mCl)-0-0(CH

3

)<C2H

5

)COOC2H5]2 CH2[o-(C6

H3mCl)-0-0(C2H

5

)2COOH]2 <OH3)2C-i[o-<C6H3

niCl)-0-C[(CH

3

)2COOH]

2 .(CH3

)2Ci[o-(C

6

H3mCl)-0-C(CH3)2COOC

2

H

5

]2 (CH3

)

2

C[pH(C

tí

H3oCl)-0-Ci(CH

3

)

2

COOH]2 (CH3)i

(C2H5)C[p-C

6

H

4

OC(CH3)

2

COOH]

2 (OH3)!(C2H5)0[p-C6H4

OC(CH3)

2

COOC

2

H

5

]2 (CH3

)i(C2H

5

>C![p^C6H40C(CH

3

)2CONH2]2 (CH3)1

(C2H5)Ci[p-C6H40Ci(CH3){C2H

5

)COOH]2 (CH3

)(C

2

H

5

)a[o-(C

B

H

3

mCl)-0-C<CH

3

)

2

COOH]

2 (CH3)(C2H5)Q[o-(CH3

m:I)-0-C(CH

3

)

2

COOH]2 (CH3

)i(CH2CH2CH3)0[p-C

6

H40C(CH3)

2

COOH]2 (C2H5)2Cl[p-CoH4

00(CH3)

2

COOH]2 (C2H5)2CÍ[PHC6

H

4

OC(CH3)2COOC2H5]2 (C2H5)20[p-C6

H40C(OH

3

)2CONH2]2 (C2H5)2

0[p^C6H40ia(CH3)(C

2

H5)COOH]2 (C2H5)2Ci[p-C6

H

4

OC(C2H

5

)

2

COOH]2 (C2H5)2Ci[o-(C6H3

mCl)-0-0(CH

3

)2COOH]

2 <CH3

) (CH2CH2CH3) a[p-C6H40C(CH3)2COOC

2

H

5

]2 (CH3) (CH2CH2

CH3)Q[

í

p-C

6

H40C(CH3)

(C2

H

5

)COOH]2 (CH3)i(nC3H7

)O[0^(C

6

H3mCl)-O-C(CH3)2COOH]2 (Cz

H

5

)(n.C

3

H7)O[p-C6H

4

0O(CH3)2COOH]2 (C2H5

)(nC

3

H

7

)0[p-C6H40C(CH3)2COOC2H5]2 (C2H5)í(n-C3H7)Cl[pHC6

H

4

OC(CH

3

)

2

CONH

2

]2 (C2H5)i(nC3H7

)0[p-C

6

H40Q(CH3)(C2H5)COOH]2 (C2H5

)!(:nC3H

7

)C{o-(C6H

3

mCl)-0-G(CH

3

)2COOH]2 {nC3

H

7

)2Q[p-C6H

4

OC(CH

3

)2COOH]9 (CH3CH2CH2

)

2

0[p-C

6

H

4

OC(CH3)2COOC2H5]2 (:nC3H7

)

2

0[p-C6H

4

00(CH

3

)

(C2

H

5

)COOH]

2 (nCgHTjaCio-iCßHsmClJ-O-OiCHsiaCOOHla (CH3)i(nC

4

H

9

)0[o-(CeH

4

OCi(CH

3

)2COOH]2 (CH3

>(nC4H9)0[p^C

6

H4OCi(iCH3)

2

COOC

2

H5]2 (CH3).(ínC4H9)0[p-C6H40C,(CH3)2

OONHCH(CH3)2]

) (CH3)i(nC4

H9)CI[p-C

6

H40G(CH3) (C

2

H

5

)COOHl2 (CH3

)

(nCíHgJCfp-Cel^OC (C2

H

5

)

2

COOH]2 (C2H5){nC4H9)0[o-(C6H3

m.Cl)-0-C(CH3)2COOH]2 (C2H5>(nC4H9

)0[o-(C

6

H3mCl)-0-C(CH

3

)(C

2

H

5

)COOH]2 <C2

H5)i(nC4H

9

)O[0-(C

6

H3mCl)-O-C(CH

3

)2-COOC2

H

5

]

2 (nC3

H

7

)(nC4H

9

)ODp-C6H40C(CH3)2COOH]2 (!

nC3H

7

)

1

(nC4H

9

)0[p-C

6

H40C(CH

3

)2COOC

2

H5]2 (nC3H7)(nC4H9)Q[p-C6H4

00(CH

3

)2CO;NHC2H5]2 (riC3H7)(nC4H9

)C)[p-C6H40C(CH3),(C

2

H5)COOH]2 (nC3H7)(nC4H9>Q[o^(C6H3oCl)-O^C(CH3)2COOH]2 (niC4H9

)2C[p-C6H40Ci(CH3)2COOH]2 (nC4H9

)2Q[p-C

6

H

4

OC(CH3)2COOC2H5]2 (nC4H9)20[p^C6H40C(CH3)(C2

H

5

)COOH]2