202820. lajstromszámú szabadalom • Hatóanyagként propénkarbonsav-származékokat tartalmazó fungicid készítmények és eljárás a hatóanyagok előállítására

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HU 202 820 B

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V. táblázat folytatása

Atáblá- Avegyü- Frekven- NMR spektrum vonalai, ppm

zat sorlet sorcia

száma száma MHz

II.

93.

270

3,60 (3H, s), 3,75 (3H, s), 3,90 (3H, s), 3,94 (3H, s), 5,67 (1H, s), 6,76 (1H, t), 6,84 (2H, m), 7,00 (1H, d), 7,15 (1H, m), 7,25-7,32 (2H, m), 7,48 (1H, s)

II.

96.

270

3,61 (3H, s), 3,75 (3H, s), 6,75 (1H, t), 6,83 (1H, dd), 6,95 (1H, dd), 7,07 (1H, d), 7,18 (1H, m),

7,29-7,37 (3H, m), 7,49 (1H, s)

II.

97.

13C NMR spektrum vonalai (67,7 MHz): 51,25,61,59,106,54,

107,41, 110,85, 114,%, 115,45, 119,58, 123,72, 125,06, 128,90, 130,05, 132,41, 152,29, 153,57, 158,81, 160,03, 160,13, 160,22, 167,49, 169,95 ppm

II.

98.

270

2,72 (3H, s), 3,60 (3H, s), 3,77 (3H, s), 5,08 (2H, s), 6,5-7,4 (9H, m), 7,48 (1H, s)

II.

99.

270

3,60 (3H, s), 3,74 (3H, s), 5,50 (2H, s),

6,92-7,0 (2H, m), 7,09-7,36 (9H, m), 7,47 (1H, s), 7,50 (1H, d)

II.

100.

270

3,60 (3H, s), 3,75 (3H, s), 5,33 (2H, s), 6,90-6,% (2H, m), 7,06-7,18 (3H, m), 7,24-7,34 (3H, m), 7,49 (1H, s), 8,07 (1H, d), 8,14 (1H, d), 8,28 (1H, s)

II.

101.

270

3,60 (3H, s), 3,75 (3H, s), 5,31 (2H, s),

6,90-6,99 (2H, m), 7,06 (1H, s), 7,10-7,18 (2H, m), 7,25-7,34 (3H, m), 7,49 (1H, s), 8,17 (2H, s)

II.

102.

270

3,60 (3H, s), 3,75 (3H, s), 5,50 (2H, s),

6,89-6,99 (3H, m), 7,1-7,42 (7H, m), 7,49 (1H, s), 7,62 (1H, t), 7,71 (1H, d), 7,83 (1H, d), 8,0 (1H, d)

II.

103.

270

3,60 (3H, s), 3,77 (3H, s), 5,49 (2H, s),

6,90-6,98 (2H, m), 7,0 (1H, d), 7,08-7,20 (3H, m), 7,24-7,33 (3H, m), 7,39 (1H, d), 7,49 (1H, s)

II.

104.

270

3,44 (3H, s), 3,70 (3H, s), 5,09 (2H, s), 6,82 (2H, d), 6,90 (1H, s), 7,0-7,14 (4H, m), 7,16-7,36 (3H, m), 7,49 (lH,s), 8,05 (2H,d)

II.

105.

270

3,60 (3H, s), 3,75 (3H, s), 5,38 (2H, s), 6,82-6,98 (3H, m), 7,05-7,20 (3H, m), 7,20-7,35 (3H, m), 7,48 (1H, s), 7,78 (1H, d), 8,43 (1H, s)

II.

106.

270

3,60 (3H, s), 3,76 (3H, s), 6,74-738 (9H, m), 7,48 (1H, s), 7,98 (1H, m), 830 (1H, m)

n.

107.

270

(3,60 (3H, s), 3,76 (3H, s), 6,73-737 (9H, m), 7,49 (1H, s), 8,45 (1H, m), 9,03 (1H, m)

ii.

270.

270

3,61 (3H, s), 3,78 (3H, s), 6,28 (1H, m), 6,70 (2H, m), 6,9-73 (9H, m), 7,48 (1H, s), 935 (1H, széles s)

ii.

271.

270

3,60 (3H, s), 3,74 (3H, s), 6,74-7,39 (9H, m), 730 (lH,s), 8,32 (lH,m)

ii.

272.

270

232 (3H, s), 234 (3H, s), 3,60 (3H, s), 3,76 (3H, s), 6,72-7,35 (8H, m), 7,49 (1H, s), 8,00 (1H, s)

ii.

273.

270

3,60 (3H, s), 3,72 (3H, s), 6,72-7,36 (8H, m), 730 (lH,s), 8,26 (2H,m)

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