202364. lajstromszámú szabadalom • Hatóanyagként (p-fenoxi-fenoxi)-metil-heteroaromás vegyületeket tartalmazó inszekticid készítmények és eljárás a hatóanyagok előállítására

1

HU 202364 B

2

Vegyület

száma

R1

R2

R3

R4

R5

R6 n Fizikai állandó (Op. *C)

15.5

3-Br

H

H

H

4-CH3

ch3 1

15.6

3-CFj

H

H

H

4-CH3

CH3 1

15.7

3-CH3

H

H

H

4-CH3

ch3 1

15.8

3-C2H5

H

H

H

4-CH3

ch3 1

15.9

3-OCH3

H

H

H

4-CH3

CH3 1

15.10

3-OC2H5

H

H

H

4-CH3

CH3 1

15.11

4-F

H

H

H

4-CHj

CH3 1

15.12

3-F

H

H

H

4-OCHj

CH3 1

15.13

3-C1

H

H

H

4-OCH3

ch3 1

15.14

3-Br

H

H

H

4-OCH3

ch3 1

15.15

3-CF3

H

H

H

4-OCH3

ch3 1

15.16

3-CH3

H

H

H

4-OCHj

ch3 1

15.17

3-C2H5

H

H

H

4-OCH3

ch3 1

15.18

3-OCH3

H

H

H

4-OCH3

ch3 1

15.19

3-OC2H5

H

H

H

4-OCH3

ch3 1

15.20

4-F

H

H

H

4-OCH3

ch3 1

15.21

3-F

H

H

ch3

4-CH3

ch3 1

15.22

3-C1

H

H

ch3

4-CH3

ch3 1

15.23

3-Br

H

H

ch3

4-CH3

CH3 1

15.24

3-CF3

H

H

CH3

4-CHj

CH3 1

15.25

3-CH3

H

H

ch3

4-CHj

CHj 1

15.26

3-C2H3

H

H

CHj

4-CHj

CH3 1

15.27

3-OCH3

H

H

CHj

4-CHj

CH3 1

15.28

3-OC2H5

H

H

CHj

4-CH,

CHj 1

15.29

4-F

H

H

CH3

4-CHj

CHj 1

15.30

3-F

H

H

ch3

4-OCHj

CHj 1

15.31

3-Cl

H

H

ch3

4-OCHj

CHj 1

15.32

3-Br

H

H

ch3

4-OCH3

CHj 1

15.33

3-CF3

H

H

ch3

4-OCHj

CHj 1

15.34

3-CHj

H

H

ch3

4-OCHj

CHj 1

15.35

3-C2H5

H

H

CHj

4-OCH3

CHj 1

15.36

3-OCH3

H

H

CHj

4-OCHj

CHj 1

15.37

3-OC2H5

H

H

ch3

4-OCHj

CHj 1

15.38

4-F

H

H

ch3

4-OCHj

CHj 1

15.39

3-F

H

3-F

H

5-CH3

CHj 1

15.40

3-C1

H

3-F

H

5-CH3

CHj 1

15.41

3-Br

H

3-F

H

5-CH3

CHj 1

15.42

3-CF3

H

3-F

H

5-CHj

CHj 1

15.43

3-CH3

H

3-F

H

5-CH3

CHj 1

15.44

3-C2H5

H

3-F

H

5-CHj

CHj 1

15.45

3-OCH3

H

3-F

H

5-CHj

CHj 1

15.46

3-OC2H5

H

3-F

H

5-CH3

CHj 1

15.47

4-F

H

3-F

H

5-CHj

CHj 1

15.48

H

H

H

H

5-Í-C3H7

CHj 1 300-MHz-'H- NMR CDCI3 [ppm]: 4,98(S)

15.49

H

H

H

H

5-Ciklopropil

CHj 1 57-58

15.50

3-F

H

H

H

5-Ciklopropil

CHj 1 46-48

15.51

3-C1

H

H

H

5-Ciklopropil

CHj 1 89-90

15.52

3-Br

H

H

H

5-Ciklopropil

CHj 1 92-93

15.53

3-CF3

H

H

H

5-Ciklopropil

CHj 1 57-58

15.54

3-OCH3

H

H

H

5-Ciklopropil

CHj 1 88-89

15.55

3-CHj

H

H

H

5-Ciklopropil

CHj 1

15.56

3-C2H5

H

H

H

5-Ciklopropil

CHj 1 olaj IR: 1508, 1449, 1015 1010, 855, 848 cm 1

15.57

3-C1

4-F

H

H

5-Ciklopropil

CHj 1

15.58

H

H

H

H

5-CH3

Ciklo- 1 propil

18