167427. lajstromszámú szabadalom • N-foszfinil-, illetve foszfinoetionil-amidineket hatóanyagként tartalmazó kártevőírtószerek
167427 17 18 R-i R2 R3 R4 R5 X Y Fizikai adatok H 14. CH3O 15. CH3O 16. CH3O CH3 CH3 CH3 H CH3 H CH3 -CH2 — O H CH3 -CH2 - I H 1 -CH2 -S O n25 D= 1,5278 S O n25D = 1,5252 S O n25D =l,5409 O 17. CH3 0 CH3 CH3 CH3 CH3 O S n25 D = l,5149 18. CH3 0 CH3 H —CH 2--CH2 -O—CH2 —CH 2 — O S n25 D =1,5349 19. CH3 0 CH3 H —CH 2--CH2 -O—CH2 —CH 2 — S O n25 D =l,5341 20. CH3 0 CH3 H CH3 CH3 O O n20 D=1.4757 21. C2 H 5 0 (n)C3 H 7 H CH3 CH3 O S n20 D =1,5085 10. C2 H 5 0 C2 H 5 H CH3 CH3 O S n25 D = l,5138 22. CH3O CH3 H —CH 2--CH2 —CH 2—CH2—CH2— 0 s n20 D = 1,5445 23. C2H5O (n)C3 H 7 H —CH 2--CH2 —CH 2—CH2—CH2— 0 s n25 D =1,5225 24. CH3 0 CH3 H —CH 2--CH2 —CH 2—CH2—CH2— 0 0 n20 D = l,4971 25. C2H5O C2H5 H CH3 CH3 s 0 n25 D =1,5275 A C2H5O H CH3 CH3 0 s X C2 H 5 0 (n)C3 H 7 H C2 H 5 C2H5 0 s n25 D = 1,5002 26. CH3O CH3 H C2 H5 C2H5 0 s n25 D =1,5145 27. CH3 0 CH3 H C2H5 C2H5 0 0 n25 D = 1,4649 28. C2 H 5 0 CH3 H —CH 2--CH2 -O—CH2 —CH 2 — 0 s ^50=1^269 29. C2 H 5 0 C2H5 H C2H5 C2 Hs s 0 n25 D = 1,4989 30. C2 H 5 0 C2H5 H —CH 2--CH2 -O—CH2 —CH 2 — s 0 n25 D =l,5143 11. CH3 0 C2H5 H CH3 CH3 0 s n25 D =1,5384 31. CH3O (n)C3 H 7 H CH3 CH3 0 s n25 D = l,5120 2. CH3 0 CH2 =CH—CH 2 H CH3 CH3 0 s n25 D = 1,5379 C C2 H 5 0 (n)C3 H 7 H —CH 2--CH2 -O—CH2 —CH 2 — 0 s B C2 H 5 0 CH2 =CH—CH 2 H —CH 2--CH2 -O—CH2 —CH 2 — 0 s 32. CH3O CH3 H —CH 2--CH= =CH2 —CH2—CH= =CH2 s 0 n25 D = 1,5187 33. CH3 0 C2H5 H -CH2 -CH= ^CH2 —CH2—CH= =CH2 O S n25 D =l,5229 4. CH3O (n)C3 H 7 H —CH 2--CH= :CH 2 —CH2—0x1= =CH2 O S n25 D = 1,5221 5. CH3O CH=C—CH2 — H —CHa-CH= :CH 2 —CH2—CH= =CH2 O S n25 o=1,5438 6. CH3 0 CH=C—CH2 — H —CH 2--CH= ;CH 2 —CI^—CH= =CH2 O S n25 D =1,5479 7. CH3O (n)C6 H 13 H —CH 2--CH= :CH 2 —CH2—CH= =CH2 O S n25 D = l,5191 34. CH3O CH3 H —CH 2--CH2 —CH 2—CH2—CH2— S O 1 Op. 35 C° 35. CH3 0 C2H5 H —CH 2--CH2 -CH2 —CH 2 —CH 2 — O S n25 D = 1,5303 36. CH3 0 (n)C3 H 7 H —CH 2--CH2 —CH 2-r-CH 2 —CH2— O S n25 D =1,5265 37. CH3 0 CH2 =CH—CH 2 -H —CH 2--CH2 -CH2 —CH2—CH 2 — O S n25 D =1,5379 8. CH3 0 CH=C—CH2 — H —CH 2--CH2 —CH 2—CH2—CH2— O S n25 D =1,5411 38. CH3 0 (n)C7 H 15 . H —CH 2--CH2 —CH 2—CH2—CH2— O S n25 D = 1,5406 39. C2 H s O (n)C3 H 7 H CH3 CH3 s s n23 D =1,5488 40. C2 H 5 0 C2 H 5 H CH3 CH3 0 s n23 D = 1,5288 41. C2 H5 C2H5 H C2 H 5 C2H5 s 0 n23 D = 1,5262 42. C2 H5 C2 H 5 H C2 H 5 C2 H 5 s 0 n23 D =1,5018 43. C2 H 5 C2 H5 H C2 H 5 C2 H5 0 s n23 D =1,5097 2. példa A) Inszekticid hatás az emésztőcsatornán keresztül Gyapotnövényeket 0,05% hatóanyagtartalmú vizes emulzióval (amelyet 10%-os emuigálható koncentrátumból készítettünk) permeteztünk be. A permetlé rászáradása után a gyapotnövényeket Spodoptera litoralis vagy Heliothis virescens lárvákkal (L3 ) telepítettük be. A kísérleteket 24 C°-on 60% viszonylagos légnedvességű térben végeztük. 55 60 100%-os pusztulás ideje (óra) Vegyület Leptinotarsa Dysdercus decemlineata fasciatus 17 24 18 24 24 21 24 — 10 48 48 22 4 24 23 24 — 25 48 — A 24 — 1 24 24 9
